{"id":1166,"date":"2020-09-22T10:30:12","date_gmt":"2020-09-22T01:30:12","guid":{"rendered":"https:\/\/mitsudo.net\/?p=1166"},"modified":"2020-12-08T10:10:42","modified_gmt":"2020-12-08T01:10:42","slug":"integrated-synthesis-of-thienyl-thioethers-and-thieno32-bthiophenes-via-benzobthiophen-3-one","status":"publish","type":"post","link":"https:\/\/mitsudo.net\/en\/integrated-synthesis-of-thienyl-thioethers-and-thieno32-bthiophenes-via-benzobthiophen-3-one\/","title":{"rendered":"Integrated Synthesis of Thienyl Thioethers and Thieno[3,2-<i>b<\/i>]thiophenes via Benzothiophen-3(2<i>H<\/i>)-ones"},"content":{"rendered":"<p>Koichi Mitsudo,* Nanae Habara, Yoshiaki Kobashi, Yuji Kurimoto, Hiroki Mandai, Seiji Suga*<br \/>\n<em>Synlett<\/em> <strong>2020<\/strong>, <em>31<\/em>, 1947\u20131952.<br \/>\n<span>DOI: <a href=\"https:\/\/doi.org\/10.1055\/s-0040-1707280\" target=\"_blank\" rel=\"noopener noreferrer\">10.1055\/s-0040-1707280<\/a><br \/>\n<img decoding=\"async\" src=\"https:\/\/mitsudo.net\/wp-content\/uploads\/2020\/08\/habara-synlett.png\" alt=\"\" width=\"522\" height=\"200\" class=\"alignnone size-full wp-image-1255\" \/><\/span><\/p>\n<p>Here is described a one-pot procedure for the synthesis of thienyl thioethers. Several thienyl thioethers were successfully synthesized by a TfOH-promoted Friedel\u2013Crafts-type cyclization, a subsequent nucleophilic attack by an arenethiol, and dehydration. This method was applicable to the synthesis of thienoacenes by a Pd-catalyzed dehydrogenative cyclization.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Koichi Mitsudo,* Nanae Habara, Yoshiaki Kobashi, Yuji Kurimoto, Hiroki Mandai, Seiji Suga* Synlett 2020, 31, 1947\u20131952. DOI: 10.1055\/s-0040-1707280 Here is described a one-pot procedure for the synthe [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":1255,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_locale":"en_US","_original_post":"https:\/\/mitsudo.net\/?p=1160","footnotes":""},"categories":[15,14],"tags":[31,18,43],"class_list":["post-1166","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-15","category-paper","tag-chemistry","tag-thienoacene","tag-thioether","en-US"],"_links":{"self":[{"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/posts\/1166","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/comments?post=1166"}],"version-history":[{"count":7,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/posts\/1166\/revisions"}],"predecessor-version":[{"id":1308,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/posts\/1166\/revisions\/1308"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/media\/1255"}],"wp:attachment":[{"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/media?parent=1166"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/categories?post=1166"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/mitsudo.net\/wp-json\/wp\/v2\/tags?post=1166"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}